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This is the Safari online edition of the printed book.

The classic guide to mixtures, completely updated with new models, theories, examples, and data.

Efficient separation operations and many other chemical processes depend upon a thorough understanding of the properties of gaseous and liquid mixtures. Molecular Thermodynamics of Fluid-Phase Equilibria, Third Edition is a systematic, practical guide to interpreting, correlating, and predicting thermodynamic properties used in mixture-related phase-equilibrium calculations.

Completely updated, this edition reflects the growing maturity of techniques grounded in applied statistical thermodynamics and molecular simulation, while relying on classical thermodynamics, molecular physics, and physical chemistry wherever these fields offer superior solutions. Detailed new coverage includes:

  • Techniques for improving separation processes and making them more environmentally friendly.

  • Theoretical concepts enabling the description and interpretation of solution properties.

  • New models, notably the lattice-fluid and statistical associated-fluid theories.

  • Polymer solutions, including gas-polymer equilibria, polymer blends, membranes, and gels.

  • Electrolyte solutions, including semi-empirical models for solutions containing salts or volatile electrolytes.

Coverage also includes: fundamentals of classical thermodynamics of phase equilibria; thermodynamic properties from volumetric data; intermolecular forces; fugacities in gas and liquid mixtures; solubilities of gases and solids in liquids; high-pressure phase equilibria; virial coefficients for quantum gases; and much more.

Throughout, Molecular Thermodynamics of Fluid-Phase Equilibria strikes a perfect balance between empirical techniques and theory, and is replete with useful examples and experimental data. More than ever, it is the essential resource for engineers, chemists, and other professionals working with mixtures and related processes.

Amazon.com® Reader Reviews (Ranked by Helpfulness)

Average Amazon.com® Rating: 4.0 out of 5 rating Based on 7 Ratings

Good solution thermo, but don't get rid of Smith & Van Ness - 2000-11-23
Reviewer Rating: 1 star rating2 star rating3 star rating4 star rating5 star rating
This is the text that is used for graduate ChE thermo at Georgia Tech. I found many of the chapters to be very useful and complete. For example, the chapters on estimating fugacities and solubilities in gases and liquids were very well written. However, I found the treatment of some topics, such as equations of state and supercritical fluids to be somewhat superficial and not developed very well in general. Smith & Van Ness and The Properties of Gases and Liquids were useful supplements.

Smith & Van Hess preferable! - 2004-01-12
Reviewer Rating: 1 star rating2 star rating3 star rating4 star rating5 star rating
This book is used as graduate text for GTech, ChBE course, and suffices in context of summarizing a large amount of material on fugacities in mixtures, empirical methods used for prediction and analysis of phase euilibria problems. With no previous exposure to Chemical Engineering Thermodynamics, I found Smith and Van Hess to be greatly helpful in explaining basic concepts, and providing a lucid, logical development of the subject. While Prausnitz dwells at length on the behavior of mixtures, the development of the subject leaves one wanting for a lot more, and hence this book will always need atleat one complementary text like Smith's book to be a useful text. The topics explained really well in the text include fugacities in gas and liquid mixtures, and calculation of solubilities of solids or gases in liquids. Other areas of thermodynamics are either ignored or coverage is sketchy (for examples treatment of polymers, electrolytes, use of statistical mechanics, etc).

Errata - 2000-06-18
Reviewer Rating: 1 star rating2 star rating3 star rating4 star rating5 star rating
En la Ec. 6-122 pg. 264 el subindice del tercer termino de la derecha de la ecuacion: phi* dice 2 debe decir 1.

Por favor si tienen un Fe de Erratas comunicarlo a todos los usuarios.

El libro es excelente. gracias

Clearly written , Very good book - 2001-07-21
Reviewer Rating: 1 star rating2 star rating3 star rating4 star rating5 star rating
The book explains clearly the subjects making easy to understand the topics. I would suggest chem. eng to use it as a tool for understanding any specific subject in phase equilibria. It points out clearly the principles. Any book written by Dr. Prausnitz has high quality.

Simple and interesting... - 2000-04-13
Reviewer Rating: 1 star rating2 star rating3 star rating4 star rating5 star rating
I found this book easy to read about some topics that others books make to difficult to understand. I widely recommend this book...

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