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C ONTENTS P REFACE TO C HEMICAL S ENSORS : C OMPREHENSIVE S ENSORS T ECHNOLOGIES P REFACE TO V OLUME 5: E LECTROCHEMICAL AND O PTICAL S ENSORS A BOUT THE E DITOR C ONTRIBUTORS 1 E LECTROCHEMICAL G AS S ENSORS : F UNDAMENTALS , F ABRICATION , AND P ARAMETERS J. R. Stetter G. Korotcenkov X. Zeng Y. Tang Y. Liu 1 Introduction 2 Fundamentals of Electrochemistry for Gas Sensors 2.1 Potential and Potentiometry 2.2 Current, Charge, and Amperometry 2.3 Conductivity/Resistance and Conductometry 3 Types of Gaseous Interactions in Sensing 3.1 Gas/Electrolyte Interactions 3.2 Gas/Electrode Interactions 4 Fundamentals of Electrochemical Gas Sensors 4.1 Amperometric Gas Sensors 4.2 Potentiometric Gas Sensors 4.3 Conductometric Gas Sensors 5 Analytes 6 Electrochemical Gas Sensor Designs and Materials 6.1 Electrolytes 6.2 Membranes 6.3 Electrodes xv xix xxi xxiii 1 1 2 3 5 7 7 8 12 15 15 19 22 23 23 24 38 38 v