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Just pressing together a section of n-type material to a p-type material cannot produce a rectifying homojunction. In order to produce a proper p-n homojunction, both types of semiconductors should be a single crystal, but divided into p-type and n-type impurity regions. This can be done in various ways. The semiconductor diodes are classified depending upon the method of constructions as:
Grown homojunction
Alloy homojunction
Diffused homojunction
Epitaxial plannar